Here are a few things worth checking.
1. Check processed messages: to see if the messages are leaving the system and not reaching their intended recipients.
2. Check queued messages : to see if the messages are being generated and simply have not left the system yet.
3. Ensure, that the approver collaborator is not silent
4. Ensure, that document phase has workflow associated with it.
5. Ensure, that the correct mail message template ( Workflow Approval Request ) is properly configured to send emails to buyers.
Then we will have a better idea of what the issue may be...
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