Active document splitting means document splitting basing on the Business Transaction/Transaction Variant assigned to the document type and the Item Category assigned to the GL account. System determines and does the splitting of each line item in the document, basing on the configuration you have done. You have control over active splitting.
Passive splitting is something that you do not have control over. System takes the document splitting characteristics from the original document that it is referencing, for example, a reversal document that always references to the original document that is being reversed. The configuration that you do does not affect passive splitting.
See the following example.
http://help.sap.com/erp2005_ehp_04/helpdata/EN/49/11da8b97244a19e10000000a42189b/content.htm
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