You can't assign number series directly at profit center level but you can define document type based on profit center and then define number series accordingly.hope your problem get solved.
If you have new GL and PCA active, it would be very difficult to have Document Types assigned at profit center level. The document types are assigned at company code level and not profit center. There would be many transactions which would have multiple profit centers. How would you seggregate them, even if you use different document types as suggested for various profit centers?? Morever, most of the posting in FI come from other modules and are posted by the system because of the transactions in other modules. So it is practically not feasible to have profit center wise document numbers.
However, for Indian Scenario, you can have SD Tax Invoices for every plant, where billing is done. Secondly, SAP has delivered excise documents to be numbered differently for every excise registration.This is to meet the Indian Reporting requirements.
Further, pls refere the postings in SDN before posting a question. There are lot of replies to your queries.
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