It's stored in C:\Users\<userid>\AppData\Roaming\SAP\Common\saplogon.ini
Just take a copy and restore it to your new machine.
To add to other input - this may not be necessary, actually. Many companies already include all the relevant connections in their SAP GUI installations. Or at least IT / Help Desk should already have a standard corporate INI file somewhere.
Unless you've added some connections manually (in which case the most reliable way to capture such info is just to take a screenshot of the connection info screen), reach out to local Help Desk for assistance with this.
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