The decimals defined in your user profile are your preferences how numbers will be shown in your SAP system to you.
How decimals in a purchase order are printed depends on the country settings for the country of the vendor. customizing transaction OY01
I would recommend to keep it as SAP designed it, as you have to imagine that the receiver of your PO must be able to understand what you want, otherwise it may happen that you get hundred thousand instead of just 100
just depending what the recipient understands when seeing
100.000 or 100,000
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