Pls check this link
http://help.sap.com/saphelp_nw04/helpdata/en/75/c80b424c6cc717e10000000a155106/content.htm
I found the solution:
1. In the J2EE installation folder, find the following directory:
\services\servlet_jsp\work\jspTemp\irj\root\WEB-INF\plugins\portal\services\usermanagement\data.
2. Delete 'verify.*' and ticketKeyStore files.
3. Restart portal.
New verify.der verify.pse and ticketKeyStore files will be generated. After that I applied new verify.der to R/3 system via 'STRUSTSSO2' transaction and everything is working fine.
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