Hi Bharath,
Yes.You can define Rule for determination of parties in Opportunities based on the Document types.
Try the below steps :-
1. Hover over the (Beta) Adminstration workcenter and select Sales and Marketing View
2. Choose " Define Rules for Opportunity Rules" under the Rules section
3.Add a New Row and define the respective condition(In your case,you can go with the Document Types)
Note :
Some time Document Type will not available,in that case,Choose "Adapt Columns" and select the Document Type as the parameter.
Regards
Logan
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