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Alfred
Yes, you can certainly upgrade from R/3 4.7 to ECC 6.0. Keeping in mind that ECC 6.0 is part of mySAP ERP 2005, your best place to start is the mySAP ERP 2005 Upgrade Master Guide. This document will list all the relevant notes you should read prior to starting your upgrade, as well as a host of other relevant information.
To obtain this document, go to the SAP Service Marketplace at http://service.sap.com/instguides, then navigate to mySAP Business Suite Applications -> mySAP ERP -> mySAP ERP 2005 -> Upgrade.
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