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Segment Field in PO/PR

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Dear Gurus,

I am in a new project where we decided segment usage, I have created segments and also activated document splitting for segment derivation, I have activated all segment configurations but we can not create materials project basis that's why I can not assign profit center to material master in order to derive segment, is there another way to use segment field for capex purchases? I have checked configuration in material management but couldn't activated segment field in ME21N and ME51N screens, I would be very glad If someone could guide me regarding that issue.

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