You can create a manual invoice request (no reference to preceding documents, no inventory movement) using the webservice "Maintain customer invoice requests" accessed from the Application & User Management WorkCenter > service Explorer view.
"The web service interface Manage Customer Invoice Request In enables you to connect external applications to your Financials on Demand system and to create and edit customer invoice requests in your system. The web service interface Manage Customer Invoice Request In is relevant if your company wants to manage customer invoice requests from external applications."
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