First of all, let me tell you that sap.m tile container is deprecated. It was available till 1.50 version. So if you want to use sap.m tile container with the latest UI5 version it will create some problem. Recommended using sap.m.GenericTile instead of sap.m tile container.
Now To answer your question sap.m tile container doesn't have any default property by which you can align tiles to left.nYou have to use Custom css to do so.
Though I am not very sure about your requirement, you might try sap.ushell.ui.launchpad.GridContainer which has more properties and its difault view is left alinged. This is a default container for Fiori Launchpad. Theme Fiori 3.
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