Enter a valid Country Key while creating a Central Requisition

HI Guru's,

We are trying to setup central Requisition in one of our System.and we have an error Enter a valid Country Key in Fiori backend system.

Steps

- Completed the technical like RFC and alias system and Functional configs Hub activation and user defaults etc.

- Logged in as an employee in Fiori and opened the App- Create Purchase requisition

-Click on Create Own item. The App is in loading status for several minutes.

- in the Fiori GUI system in Tcode - /n/IWBEP/ERROR_LOG we have an error as "Enter a valid Country Keycp-ccode-erro.png".

Any help is appreciated.....